The first thing to do is to drag and drop your color table in Coraye or to perform a file / Open to select your color table.
Coraye is compatible with .cxf, .aco, .acb, .ase, .csv, etc ...
In the Coraye software, select your color table in the left column, then right click to select "Export" then "Export acb" or "Export ase".
Give a name before saving your file (for example: My Color Table.acb)
Open Illustrator. From the Windows tab select Swatches
Head over to the hamburger dropdown and click Open Swatch Library > Other Library.
Browse to select your color Table (.acb or .ase), then click on Open
This will show spot colors in a new swatches book.
Now, spot colors are ready to be used in your page layout.